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Enzyomics - rapid multiplex determination of enzyme activity and selectivity

ReferenceE20426
Principal Investigator / Supervisor Professor Duncan Graham
Co-Investigators /
Co-Supervisors
Dr Barry Moore
Institution University of Strathclyde
DepartmentPure and Applied Chemistry
Funding typeResearch
Value (£) 201,928
StatusCompleted
TypeResearch Grant
Start date 01/04/2004
End date 31/03/2006
Duration24 months

Abstract

A new approach to determining enzyme activity and selectivity with minimal separations will be investigated. The basis of the approach lies in using the ultra sensitive analytical technique of surface enhanced resonance Raman scattering (SERRS) combined with modified enzyme substrates. The substrates are modified in such a way that they are masked and do not produce SERRS signals until enzymatic cleavage of a scissile bond occurs to release a specific SERRS label. The intensity of the signal relates to the enzyme activity and use of multiple labels and substrates allows determination of the selectivity of the enzyme. The sensitivity of the technique is such that a few hundred enzyme molecules can be assayed and various formats will be investigated to widen the applicability of the approach and optimise the sampling format.

Summary

unavailable
Committee Closed Committee - Engineering & Biological Systems (EBS)
Research TopicsX – not assigned to a current Research Topic
Research PriorityX – Research Priority information not available
Research Initiative X - not in an Initiative
Funding SchemeX – not Funded via a specific Funding Scheme
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