Award details

Studies on guanosine triphosphate cyclohydrolase I and dihydroneopterin aldolase

ReferenceB05795
Principal Investigator / Supervisor Professor D Young
Co-Investigators /
Co-Supervisors
Institution University of Sussex
DepartmentChemistry
Funding typeResearch
Value (£) 141,492
StatusCompleted
TypeResearch Grant
Start date 01/06/1996
End date 02/12/1999
Duration42 months

Abstract

The enzymes guanosine triphosphate cyclohydrolase I and dihydroneopterin aldolase are involved in the biosynthesis of the coenzyme tetrahydrofolic acid, and GTP cyclohydrolase I is also involved in the biosynthesis of the coenzyme tetrahydrobiopterin. This makes both enzymes key targets for therapeutic intervention. We intend to study the putative Amadori rearrangement mechanism for GTP cyclohydrolase I and the stereochemical outcome of both enzymic reactions. The work will also set up useful synthetic protocols for study of dihydropteroate synthase, a target for anti-bacterial drugs. New syntheses of the reduced pterin coenzymes will be developed in the course of the work.

Summary

unavailable
Committee Closed Committee - Biomolecular Sciences (BMS)
Research TopicsX – not assigned to a current Research Topic
Research PriorityX – Research Priority information not available
Research Initiative X - not in an Initiative
Funding SchemeX – not Funded via a specific Funding Scheme
terms and conditions of use (opens in new window)
export PDF file